#METABOLOMICS WORKBENCH hormel101_20170303_113206_mwtab.txt DATATRACK_ID:858 VERSION 1 CREATED_ON April 13, 2017, 1:32 pm #PROJECT PR:PROJECT_TITLE Mayo Metabolomics Pilot and Feasibility Award: Effects of Curcumin PR:PROJECT_TITLE Supplementation on the Plasma Metabolome of Older Adults: Relation to Vascular PR:PROJECT_TITLE Function PR:PROJECT_SUMMARY Age is the major risk factor for cardiovascular diseases (CVD). Two key PR:PROJECT_SUMMARY contributors to the increased risk of CVD in middle-aged and older (MA/O) adults PR:PROJECT_SUMMARY are stiffening of the large elastic arteries and the development of vascular PR:PROJECT_SUMMARY endothelial dysfunction, indicated by impaired nitric oxide (NO)-induced PR:PROJECT_SUMMARY endothelium-dependent dilation (EDD). The mechanisms by which aging causes PR:PROJECT_SUMMARY arterial dysfunction are incompletely understood, but involve reductions in NO PR:PROJECT_SUMMARY bioavailability associated with the development of oxidative stress and PR:PROJECT_SUMMARY inflammation. Thus, establishing novel strategies to reduce arterial stiffness PR:PROJECT_SUMMARY and increase vascular endothelial function in MA/O adults by increasing NO PR:PROJECT_SUMMARY bioavailability and reducing oxidative stress and inflammation are a high PR:PROJECT_SUMMARY biomedical research priority. Curcumin is a naturally occurring phenol found in PR:PROJECT_SUMMARY the Indian spice turmeric that improves physiological function in animal models PR:PROJECT_SUMMARY of age-related diseases and is a promising nutraceutical for intervention for PR:PROJECT_SUMMARY promoting healthy aging. Our preclinical results indicate that chow supplemented PR:PROJECT_SUMMARY with curcumin reduces aortic pulse wave velocity (PWV), the most common and PR:PROJECT_SUMMARY clinically important measure of large elastic artery stiffness, restores PR:PROJECT_SUMMARY NO-mediated EDD and reduces arterial oxidative stress and inflammation in old PR:PROJECT_SUMMARY C57/BL6 mice. Preliminary data from our recently funded NIH R21 pilot grant PR:PROJECT_SUMMARY indicate that curcumin supplementation improves vascular function in humans. It PR:PROJECT_SUMMARY is possible that changes in the circulating (plasma) metabolome with oral PR:PROJECT_SUMMARY curcumin supplementation will provide insight into novel metabolic mechanisms by PR:PROJECT_SUMMARY which curcumin may improve vascular function. The goal of this project is to PR:PROJECT_SUMMARY identify key metabolic pathways that change with oral curcumin supplementation PR:PROJECT_SUMMARY and to relate those changes with improvements in vascular function in MA/O PR:PROJECT_SUMMARY adults with initial endothelial dysfunction. Metabolomic analysis of plasma PR:PROJECT_SUMMARY samples at baseline also may produce unique molecular signatures that predict PR:PROJECT_SUMMARY responsiveness (changes in vascular function) to curcumin supplementation among PR:PROJECT_SUMMARY individuals. PR:INSTITUTE Mayo Clinic PR:LAST_NAME Seals PR:FIRST_NAME Douglas PR:ADDRESS Department of Integrative Physiology University of Colorado Boulder, CO 80309 PR:EMAIL seals@colorado.edu PR:PHONE 303-492-5305 #STUDY ST:STUDY_TITLE Large Scale C18 Profiling of the Effects of Curcumin Supplementation of Older ST:STUDY_TITLE Adults: Relation to Vascular Function ST:STUDY_SUMMARY Perform large scale profiling C18 metabolite analysis related to nitric oxide ST:STUDY_SUMMARY biology, oxidative stress and inflammation in plasma before and after 12 weeks ST:STUDY_SUMMARY of oral curcumin (2000 mg/d) or placebo (double-blind, randomized) in men and ST:STUDY_SUMMARY women aged 45-79 years who are free from clinical cardiovascular disease. ST:INSTITUTE Mayo Clinic ST:LAST_NAME Seals ST:FIRST_NAME Douglas ST:ADDRESS Department of Integrative Physiology University of Colorado Boulder, CO 80309 ST:EMAIL seals@colorado.edu ST:PHONE 303-492-5305 #SUBJECT SU:SUBJECT_TYPE Human SU:SUBJECT_SPECIES Homo sapiens SU:TAXONOMY_ID 9606 #SUBJECT_SAMPLE_FACTORS: SUBJECT(optional)[tab]SAMPLE[tab]FACTORS(NAME:VALUE pairs separated by |)[tab]Additional sample data SUBJECT_SAMPLE_FACTORS 1 04jun15_004-r001 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 1 04jun15_004-r002 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 2 04jun15_005-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 2 04jun15_005-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 2 04jun15_006-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 2 04jun15_006-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 3 04jun15_007-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 3 04jun15_007-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 3 04jun15_008-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 3 04jun15_008-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 4 04jun15_009-r001 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 4 04jun15_009-r002 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 5 04jun15_010-r001 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 5 04jun15_010-r002 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 5 04jun15_011-r001 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 5 04jun15_011-r002 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 6 04jun15_012-r001 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 6 04jun15_012-r002 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 6 04jun15_013-r001 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 6 04jun15_013-r002 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 7 04jun15_014-r001 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 7 04jun15_014-r002 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 8 04jun15_015-r001 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 8 04jun15_015-r002 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 8 04jun15_016-r001 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 8 04jun15_016-r002 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 9 04jun15_017-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 9 04jun15_017-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 9 04jun15_018-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 9 04jun15_018-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 10 04jun15_019-r001 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 10 04jun15_019-r002 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 11 04jun15_020-r001 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 11 04jun15_020-r002 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 11 04jun15_021-r001 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 11 04jun15_021-r002 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 12 04jun15_022-r001 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 12 04jun15_022-r002 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 12 04jun15_023-r001 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 12 04jun15_023-r002 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 13 04jun15_024-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 13 04jun15_024-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 13 04jun15_025-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 13 04jun15_025-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 14 04jun15_026-r001 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 14 04jun15_026-r002 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 15 04jun15_027-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 15 04jun15_027-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 15 04jun15_028-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 15 04jun15_028-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 16 04jun15_029-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 16 04jun15_029-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 16 04jun15_030-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 16 04jun15_030-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 17 04jun15_031-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 17 04jun15_031-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 17 04jun15_032-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 17 04jun15_032-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 18 04jun15_033-r001 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 18 04jun15_033-r002 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 19 04jun15_034-r001 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 19 04jun15_034-r002 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 19 04jun15_035-r001 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 19 04jun15_035-r002 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 20 04jun15_038-r001 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 20 04jun15_038-r002 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 20 04jun15_039-r001 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 20 04jun15_039-r002 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 21 04jun15_040-r001 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 21 04jun15_040-r002 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 22 28may15_004-r001 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 22 28may15_004-r002 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 23 28may15_005-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 23 28may15_005-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 23 28may15_006-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 23 28may15_006-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 24 28may15_007-r001 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 24 28may15_007-r002 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 24 28may15_008-r001 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 24 28may15_008-r002 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 25 28may15_009-r001 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 25 28may15_009-r002 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 26 28may15_010-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 26 28may15_010-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 26 28may15_011-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 26 28may15_011-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 27 28may15_012-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 27 28may15_012-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 27 28may15_013-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 27 28may15_013-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 28 28may15_014-r001 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 28 28may15_014-r002 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 29 28may15_015-r001 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 29 28may15_015-r002 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 29 28may15_016-r001 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 29 28may15_016-r002 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 30 28may15_017-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 30 28may15_017-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 30 28may15_018-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 30 28may15_018-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 31 28may15_019-r001 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 31 28may15_019-r002 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 32 28may15_020-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 32 28may15_020-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 32 28may15_021-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 32 28may15_021-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 33 28may15_022-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 33 28may15_022-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 33 28may15_023-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 33 28may15_023-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 34 28may15_024-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 34 28may15_024-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 34 28may15_025-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 34 28may15_025-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 35 28may15_026-r001 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 35 28may15_026-r002 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 36 28may15_027-r001 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 36 28may15_027-r002 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 36 28may15_028-r001 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 36 28may15_028-r002 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 37 28may15_029-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 37 28may15_029-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 37 28may15_030-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 37 28may15_030-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 38 28may15_031-r001 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 38 28may15_031-r002 group:Old-Curcumin | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 38 28may15_032-r001 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 38 28may15_032-r002 group:Old-Curcumin | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 39 28may15_033-r001 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 39 28may15_033-r002 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 40 28may15_034-r001 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 40 28may15_034-r002 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 40 28may15_035-r001 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 40 28may15_035-r002 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 41 28may15_036-r001 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 41 28may15_036-r002 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 41 28may15_037-r001 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 41 28may15_037-r002 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 42 28may15_038-r001 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 42 28may15_038-r002 group:Old-Placebo | Time point:Pre ionmode=NC18 SUBJECT_SAMPLE_FACTORS 42 28may15_039-r001 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 42 28may15_039-r002 group:Old-Placebo | Time point:Post ionmode=NC18 SUBJECT_SAMPLE_FACTORS 43 28may15_040-r001 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 43 28may15_040-r002 group:young | Time point:Baseline ionmode=NC18 SUBJECT_SAMPLE_FACTORS 1 01jun15_004-r001 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 1 01jun15_004-r002 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 2 01jun15_005-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 2 01jun15_005-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 2 01jun15_006-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 2 01jun15_006-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 3 01jun15_007-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 3 01jun15_007-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 3 01jun15_008-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 3 01jun15_008-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 4 01jun15_009-r001 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 4 01jun15_009-r002 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 5 01jun15_010-r001 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 5 01jun15_010-r002 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 5 01jun15_011-r001 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 5 01jun15_011-r002 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 6 01jun15_012-r001 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 6 01jun15_012-r002 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 6 01jun15_013-r001 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 6 01jun15_013-r002 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 7 01jun15_014-r001 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 7 01jun15_014-r002 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 8 01jun15_015-r001 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 8 01jun15_015-r002 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 8 01jun15_016-r001 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 8 01jun15_016-r002 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 9 01jun15_017-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 9 01jun15_017-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 9 01jun15_018-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 9 01jun15_018-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 10 01jun15_019-r001 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 10 01jun15_019-r002 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 11 01jun15_020-r001 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 11 01jun15_020-r002 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 11 01jun15_021-r001 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 11 01jun15_021-r002 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 12 01jun15_022-r001 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 12 01jun15_022-r002 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 12 01jun15_023-r001 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 12 01jun15_023-r002 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 13 01jun15_024-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 13 01jun15_024-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 13 01jun15_025-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 13 01jun15_025-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 14 01jun15_026-r001 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 14 01jun15_026-r002 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 15 01jun15_027-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 15 01jun15_027-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 15 01jun15_028-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 15 01jun15_028-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 16 01jun15_029-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 16 01jun15_029-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 16 01jun15_030-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 16 01jun15_030-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 17 01jun15_031-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 17 01jun15_031-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 17 01jun15_032-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 17 01jun15_032-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 18 01jun15_033-r001 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 18 01jun15_033-r002 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 19 01jun15_034-r001 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 19 01jun15_034-r002 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 19 01jun15_035-r001 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 19 01jun15_035-r002 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 20 01jun15_038-r001 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 20 01jun15_038-r002 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 20 01jun15_039-r001 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 20 01jun15_039-r002 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 21 01jun15_040-r001 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 21 01jun15_040-r002 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 22 26may15_004-r001 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 22 26may15_004-r002 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 23 26may15_005-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 23 26may15_005-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 23 26may15_006-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 23 26may15_006-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 24 26may15_007-r001 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 24 26may15_007-r002 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 24 26may15_008-r001 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 24 26may15_008-r002 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 25 26may15_009-r001 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 25 26may15_009-r002 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 26 26may15_010-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 26 26may15_010-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 26 26may15_011-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 26 26may15_011-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 27 26may15_012-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 27 26may15_012-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 27 26may15_013-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 27 26may15_013-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 28 26may15_014-r001 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 28 26may15_014-r002 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 29 26may15_015-r001 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 29 26may15_015-r002 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 29 26may15_016-r001 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 29 26may15_016-r002 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 30 26may15_017-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 30 26may15_017-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 30 26may15_018-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 30 26may15_018-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 31 26may15_019-r001 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 31 26may15_019-r002 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 32 26may15_020-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 32 26may15_020-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 32 26may15_021-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 32 26may15_021-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 33 26may15_022-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 33 26may15_022-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 33 26may15_023-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 33 26may15_023-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 34 26may15_024-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 34 26may15_024-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 34 26may15_025-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 34 26may15_025-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 35 26may15_026-r001 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 35 26may15_026-r002 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 36 26may15_027-r001 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 36 26may15_027-r002 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 36 26may15_028-r001 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 36 26may15_028-r002 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 37 26may15_029-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 37 26may15_029-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 37 26may15_030-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 37 26may15_030-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 38 26may15_031-r001 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 38 26may15_031-r002 group:Old-Curcumin | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 38 26may15_032-r001 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 38 26may15_032-r002 group:Old-Curcumin | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 39 26may15_033-r001 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 39 26may15_033-r002 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 40 26may15_034-r001 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 40 26may15_034-r002 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 40 26may15_035-r001 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 40 26may15_035-r002 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 41 26may15_036-r001 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 41 26may15_036-r002 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 41 26may15_037-r001 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 41 26may15_037-r002 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 42 26may15_038-r001 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 42 26may15_038-r002 group:Old-Placebo | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 42 26may15_039-r001 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 42 26may15_039-r002 group:Old-Placebo | Time point:Post ionmode=PC18 SUBJECT_SAMPLE_FACTORS 43 26may15_040-r001 group:young | Time point:Pre ionmode=PC18 SUBJECT_SAMPLE_FACTORS 43 26may15_040-r002 group:young | Time point:Pre ionmode=PC18 #COLLECTION CO:COLLECTION_SUMMARY Healthy men & women aged 45-79 without clinical CVD, but with below normal CO:COLLECTION_SUMMARY baseline endothelial dysfunction (FMDBA < 7%). #TREATMENT TR:TREATMENT_SUMMARY "A 12-week randomized, double-blind, placebo controlled study will be conducted. TR:TREATMENT_SUMMARY After CTRC screening for inclusion/exclusion criteria, qualified subjects will TR:TREATMENT_SUMMARY be randomly assigned to 1 of 2 groups. The investigators involved in the TR:TREATMENT_SUMMARY acquisition and analysis of key outcomes will be blinded to the curcumin intake TR:TREATMENT_SUMMARY status of the subjects. With the assistance of dietary monitoring from the TR:TREATMENT_SUMMARY UC-Boulder CTRC bionutritionists, subjects will maintain their baseline diet TR:TREATMENT_SUMMARY with either unchanged (control) or enhanced curcumin intake delivered as TR:TREATMENT_SUMMARY capsules (Longvida®, Verdure Sciences): Group 1 = placebo (inert substances); TR:TREATMENT_SUMMARY Group 2 = curcumin (2000mg curcumin/day). Extensive published work has TR:TREATMENT_SUMMARY established that the curcumin dose of 2000 mg/day is well tolerated and safe. TR:TREATMENT_SUMMARY Sessions 1 & 2: Screening measurements. Session 3: Baseline measurements and TR:TREATMENT_SUMMARY blood draw. Sessions 4-8 (every other week to assess adherence and overall TR:TREATMENT_SUMMARY subject well-being): Body weight, BP, adherence, discuss any problems. Session TR:TREATMENT_SUMMARY 9: Identical to session 3 (stop intake of capsules after completion of TR:TREATMENT_SUMMARY post-testing)." #SAMPLEPREP SP:SAMPLEPREP_SUMMARY Venous blood sampling. All blood samples are handled in a similar time frame and SP:SAMPLEPREP_SUMMARY immediately spun to extract plasma and stored in our -80 freezer until ready for SP:SAMPLEPREP_SUMMARY analysis. #CHROMATOGRAPHY CH:CHROMATOGRAPHY_TYPE Reversed phase CH:INSTRUMENT_NAME Waters Acquity CH:COLUMN_NAME Waters Acquity HSS C18 (150 x 2.1mm, 1.8um) #ANALYSIS AN:ANALYSIS_TYPE MS #MS MS:MS_COMMENTS - MS:INSTRUMENT_NAME Agilent 6550 QTOF MS:INSTRUMENT_TYPE QTOF MS:MS_TYPE ESI MS:ION_MODE POSITIVE #MS_METABOLITE_DATA MS_METABOLITE_DATA:UNITS intensity MS_METABOLITE_DATA_START Samples 01jun15_004-r001 01jun15_004-r002 01jun15_005-r001 01jun15_005-r002 01jun15_006-r001 01jun15_006-r002 01jun15_007-r001 01jun15_007-r002 01jun15_008-r001 01jun15_008-r002 01jun15_009-r001 01jun15_009-r002 01jun15_010-r001 01jun15_010-r002 01jun15_011-r001 01jun15_011-r002 01jun15_012-r001 01jun15_012-r002 01jun15_013-r001 01jun15_013-r002 01jun15_014-r001 01jun15_014-r002 01jun15_015-r001 01jun15_015-r002 01jun15_016-r001 01jun15_016-r002 01jun15_017-r001 01jun15_017-r002 01jun15_018-r001 01jun15_018-r002 01jun15_019-r001 01jun15_019-r002 01jun15_020-r001 01jun15_020-r002 01jun15_021-r001 01jun15_021-r002 01jun15_022-r001 01jun15_022-r002 01jun15_023-r001 01jun15_023-r002 01jun15_024-r001 01jun15_024-r002 01jun15_025-r001 01jun15_025-r002 01jun15_026-r001 01jun15_026-r002 01jun15_027-r001 01jun15_027-r002 01jun15_028-r001 01jun15_028-r002 01jun15_029-r001 01jun15_029-r002 01jun15_030-r001 01jun15_030-r002 01jun15_031-r001 01jun15_031-r002 01jun15_032-r001 01jun15_032-r002 01jun15_033-r001 01jun15_033-r002 01jun15_034-r001 01jun15_034-r002 01jun15_035-r001 01jun15_035-r002 01jun15_038-r001 01jun15_038-r002 01jun15_039-r001 01jun15_039-r002 01jun15_040-r001 01jun15_040-r002 26may15_004-r001 26may15_004-r002 26may15_005-r001 26may15_005-r002 26may15_006-r001 26may15_006-r002 26may15_007-r001 26may15_007-r002 26may15_008-r001 26may15_008-r002 26may15_009-r001 26may15_009-r002 26may15_010-r001 26may15_010-r002 26may15_011-r001 26may15_011-r002 26may15_012-r001 26may15_012-r002 26may15_013-r001 26may15_013-r002 26may15_014-r001 26may15_014-r002 26may15_015-r001 26may15_015-r002 26may15_016-r001 26may15_016-r002 26may15_017-r001 26may15_017-r002 26may15_018-r001 26may15_018-r002 26may15_019-r001 26may15_019-r002 26may15_020-r001 26may15_020-r002 26may15_021-r001 26may15_021-r002 26may15_022-r001 26may15_022-r002 26may15_023-r001 26may15_023-r002 26may15_024-r001 26may15_024-r002 26may15_025-r001 26may15_025-r002 26may15_026-r001 26may15_026-r002 26may15_027-r001 26may15_027-r002 26may15_028-r001 26may15_028-r002 26may15_029-r001 26may15_029-r002 26may15_030-r001 26may15_030-r002 26may15_031-r001 26may15_031-r002 26may15_032-r001 26may15_032-r002 26may15_033-r001 26may15_033-r002 26may15_034-r001 26may15_034-r002 26may15_035-r001 26may15_035-r002 26may15_036-r001 26may15_036-r002 26may15_037-r001 26may15_037-r002 26may15_038-r001 26may15_038-r002 26may15_039-r001 26may15_039-r002 26may15_040-r001 26may15_040-r002 Factors group:young | Time point:Pre group:young | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:young | Time point:Pre group:young | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Post group:young | Time point:Pre group:young | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Post group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:young | Time point:Pre group:young | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Post group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:young | Time point:Pre group:young | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:young | Time point:Pre group:young | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Post group:young | Time point:Pre group:young | Time point:Pre group:young | Time point:Pre group:young | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Post group:young | Time point:Pre group:young | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:young | Time point:Pre group:young | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Post group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:young | Time point:Pre group:young | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:young | Time point:Pre group:young | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Post group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Pre group:Old-Curcumin | Time point:Post group:Old-Curcumin | Time point:Post group:young | Time point:Pre group:young | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Pre group:Old-Placebo | Time point:Post group:Old-Placebo | Time point:Post group:young | Time point:Pre group:young | Time point:Pre 252.9749@0.843182 1 1 9251 1 10001 8479 9285 11862 10207 10827 11857 9403 11723 9792 11353 1 1 9369 9208 9445 8203 7211 10771 10921 9820 8962 7030 7886 6777 8973 1 9312 9299 1 9070 10257 7751 7995 9016 1 9526 6879 9306 7037 8782 1 8745 1 6856 6925 9598 9557 9280 1 1 8027 8313 9576 1 1 7754 10015 9073 10215 9419 7907 6192 1 8242 1 1 9261 14774 14171 13724 13599 10413 1 11038 1 9214 9490 11696 11408 11257 10814 11273 12623 9331 10457 1 1 9147 12889 9393 10116 11135 9865 10604 11862 11978 12061 12009 13266 12076 13280 12059 13261 1 1 5512 1 6542 1 1 6258 5661 1 1 5986 8298 8854 9878 9367 7304 8108 8823 1 7581 9129 6569 8330 9378 1 7852 1 9866 9944 8215 1 1 1 6608 6644 180.0215@0.84397084 1 14969 1 18257 1 18387 18012 1 18401 19033 17400 19755 20788 21612 21577 20027 17910 1 16362 18124 1 18360 18515 1 18653 18038 1 15634 14786 15570 17053 16068 16330 17931 17158 17689 16396 14308 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66646 64114 1 65241 1 52310 1 54643 56797 50317 47021 53110 50542 49719 47558 54109 1 53806 55736 53829 52222 54113 53594 1 1 57611 1 60201 60476 1 58204 1 1 1 56317 60681 59213 1 50342 157.9898@0.84346044 37691 31977 60611 57885 64688 56783 73441 65253 63613 53712 53597 56865 66199 52121 60098 66338 61825 65563 57008 60885 55116 56037 59692 64638 63509 63020 49806 49979 58905 48886 57409 55981 70546 59170 58777 56640 51706 1 54522 54485 54312 53849 55100 60669 48948 58935 54827 54739 52369 53633 59459 56160 56368 58631 62266 54305 52807 57939 1 1 52285 54085 55813 52238 54101 54065 48917 44705 49869 40478 58732 60893 70329 71112 73177 69428 66700 62505 61988 65275 70159 61493 64044 61771 64645 62018 62617 58697 61680 56260 57240 62531 68986 70895 62008 64592 62680 66968 66379 62840 70061 73220 63059 60204 66316 59591 66216 63448 66918 49390 54734 51749 52364 52944 1 54329 1 56103 47053 54590 48968 48202 52306 57488 56509 52977 54808 54795 56100 58221 54904 47904 55451 53340 55878 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1 11352 1 1 10785 1 1 1 1 1 10837 10716 1 1 1 1 1 1 1 1 1 11861 1 1 12940 1 1 12405 1 14034 1 1 1 1 10886 11625 3-(Pyrazol-1-yl)-L-alanine 267366 265269 283395 267686 288129 285746 248958 244214 277425 284142 295540 304568 239818 245364 237296 207842 296578 296649 312700 323038 290228 287999 259386 217715 234463 227525 250341 1 234627 228638 356367 365778 199120 196716 231096 229034 278071 278395 277213 275567 239641 248188 217985 215375 216185 229488 202773 197713 194159 195961 205314 1 202922 204901 207547 1 210547 216172 223741 230215 226561 227126 221702 221536 276547 278200 239533 237825 247051 250434 265388 270919 206072 206303 252823 251143 218649 221865 196524 195899 298102 293695 267256 267261 281393 274993 242286 249746 250270 252708 250093 251838 269210 1 257160 266982 303153 301779 280764 281405 282645 1 268108 271029 205140 211354 251144 259867 264803 249730 234481 242000 299712 300874 251759 263774 223735 222592 220612 237389 227281 231546 285541 278555 239049 236147 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1 1 1 70019 C16 H26 N17 S3 35140 30781 119169 134017 139300 147541 121790 128169 103787 93970 86027 97013 104774 104462 123974 80224 109816 124346 75147 91400 90634 77704 95726 81295 83678 94923 105572 112906 107817 107284 1 1 129661 115394 87937 85490 132122 123094 129242 114100 134455 134263 125065 120799 116381 143932 141198 142974 152761 164539 128650 114238 107409 105635 116096 120614 116784 116495 46565 42768 108569 133865 103229 100295 153253 151205 99026 97544 114632 132561 92433 92375 124316 123242 93467 108806 132249 116660 130905 162350 94803 96287 91470 99099 112847 130458 1 127624 101883 99648 93376 99835 104714 96431 128674 144089 105878 98251 84162 81729 91101 74357 147190 130072 123736 156612 126516 142123 115723 127899 158209 158697 63027 77290 90092 80863 137798 120801 100330 111979 147400 131823 123891 95626 95086 92902 108271 107537 1 1 102955 107252 82733 98476 79283 77692 87207 103053 103270 103490 92923 103619 1 1 5,7,3',5'-Tetrahydroxy-3,6,8,4'-tetramethoxyflavone 3'-glucoside 4463 1 27217 25683 31622 32775 22215 22650 19398 19401 18652 18382 22222 24492 26986 23765 21522 24588 14183 14391 17048 16983 16961 16231 15567 15671 19981 19270 25090 21227 1 1 25570 22021 17955 18453 30339 28319 25148 23011 31117 33260 21515 23573 31462 31136 29393 31089 34218 35690 20735 21837 18811 19976 20917 23506 21858 23324 6826 6851 21944 25033 21015 18360 33228 34839 23267 22565 28596 28383 18497 18763 26746 31607 18712 19354 24273 28154 27998 37047 18074 20228 16689 14210 19657 22497 28994 26996 17053 17018 21130 20567 18393 18933 26769 25178 18969 19423 12015 10695 16882 15674 26103 25933 30250 28052 22975 23205 17746 21948 46444 44072 11623 12656 16277 18039 26743 25293 18434 18981 30089 26679 22458 20796 16330 17680 20937 20346 1 1 19485 18385 15935 17084 15534 15647 18180 19166 19198 18842 16400 17283 1 1 C10 H8 N7 O5 S 11842 1 1 1 1 1 1 1 10297 1 1 1 22279 18340 13170 1 1 1 20661 20564 12331 1 17402 1 1 23946 1 1 1 1 27738 1 8203 1 17796 1 8770 1 1 1 1 1 15577 13830 1 1 1 1 1 1 1 1 11157 1 1 1 7675 1 1 1 1 8899 17664 13618 1 1 1 1 1 1 1 1 1 1 18240 1 1 1 1 7265 1 1 1 17585 1 1 1 1 1 1 1 1 17636 1 1 1 1 7121 1 1 1 23671 1 1 13434 13575 1 1 10925 1 8655 1 16031 14645 1 1 1 1 1 1 1 1 18220 16276 1 13035 13780 1 20600 26210 1 1 19123 20986 21769 20803 16199 16062 17140 19666 22423 1 1 1 5-Methylcytidine 66238 67874 174463 126850 91849 74624 111786 84661 65889 61158 110257 91301 61480 59981 51647 42397 104548 87863 62477 60215 79043 76437 211688 197410 85571 86221 95109 82657 79907 79560 212799 212809 151607 102615 62183 51408 250583 229142 77254 66123 98507 70327 63064 56821 93203 85102 84453 55974 154609 109652 94867 71722 93881 65147 62843 62071 58224 55135 100880 76410 129380 86817 71939 58632 73797 66830 74069 58537 114987 95287 107258 101929 66799 67694 265544 259972 47875 45602 50994 54501 84794 81037 45431 41817 52357 50875 77074 73899 87314 85099 95679 93448 100426 95475 262886 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223918 3-Butynoate 14240 1 20089 18925 16051 1 1 20217 15616 1 19579 24569 16259 15499 1 1 1 18457 1 19074 19962 21058 18377 21345 1 1 1 19227 19276 12451 29809 30945 22801 22929 19584 16975 1 1 1 22244 23631 1 17278 18029 1 1 14017 1 21358 1 1 1 18260 19793 20188 18274 17495 1 1 1 1 1 1 16161 21845 19795 1 1 1 1 1 1 24504 1 25123 22043 1 20300 1 15295 20733 1 21521 19114 20685 21011 20615 1 1 19366 11085 1 19935 14919 1 16116 21764 1 15960 12500 1 17185 1 15273 1 1 1 1 1 20972 13222 13644 16754 13025 1 15342 16880 1 1 17132 1 14155 1 17667 1 16787 15514 1 27705 27280 16270 1 18088 17318 12819 14515 12779 1 16530 1 14777 17596 32371 30749 202.0458@0.9547847 42619 38808 126074 112130 95767 92051 149324 129820 117941 124957 97590 94797 104668 102081 112644 115205 120677 122193 117727 116335 112144 111751 109090 104802 111036 109300 121430 114713 120043 115843 189411 204577 133347 130619 112440 108651 94438 98467 85279 89700 108551 103393 102230 101804 95309 99436 103522 103129 95279 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13992 15827 13977 13431 14731 15163 14805 15098 14068 15515 1 1 382.1083@0.95757157 1 1 8998 1 1 1 1 9650 7010 1 1 1 1 1 1 1 1 1 1 6979 1 1 1 1 1 1 1 1 1 1 16208 16900 8836 1 1 1 5478 1 1 1 1 1 1 1 1 1 1 6740 1 1 1 1 1 7662 1 1 6996 1 1 1 1 1 6973 1 7901 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 5326 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 8356 1 1 1 6766 1 8375 1 1 1 1 1 1 1 1 1 1 1 1 17096 16901 1 1 1 1 1 1 1 1 1 1 1 1 18068 18548 (E)-2-Methylglutaconic acid 14353 19683 47932 29075 27707 28775 34182 42359 29748 31542 36195 34397 39584 41638 31603 31695 31299 30958 29177 29628 30175 26396 29541 26983 30579 28702 45373 29085 44515 30467 32047 32062 47343 33444 30369 43966 42402 39106 24857 29526 40748 42750 28838 29022 29507 30138 1 38115 1 27723 29945 32592 29861 35266 25829 23665 30391 30430 20078 19944 35597 48332 32297 24974 45206 31960 20569 31812 28469 27616 25570 26915 33385 31233 52728 30013 44805 48224 31394 25523 26222 28654 27709 29760 45603 33618 38662 32720 26361 28828 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1 1 16331 16892 13623 20632 1 1,6-Anhydro-?-D-glucose 1 1 171574 164217 144697 150871 180468 170850 159565 169694 140214 110061 156706 163242 162495 162428 156574 163699 156756 163216 152876 157577 139611 147231 165681 150012 172864 167618 163502 161440 177438 169668 180143 175595 165674 150953 151146 153195 141604 1 155225 170168 149849 151030 163671 159949 172327 151944 166300 145964 172780 162386 181636 176914 151967 149498 159697 152880 103784 110508 175129 195043 1 178758 172248 179366 124592 127848 145266 154776 1 128916 168434 155440 173688 158955 168436 165209 155056 147946 149487 143794 148445 152580 165311 168473 163363 170882 146979 156293 121250 118730 134596 140229 134326 133575 168375 154163 163925 149655 129059 129201 145230 140622 136317 136290 157397 158134 163079 169766 126753 139370 141930 151724 165568 177205 154216 155272 144076 151288 142720 144543 140562 136830 135283 154124 153799 146375 152100 152756 175388 163680 159378 152141 136298 133737 136405 138179 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152749 154534 161207 156594 1 1 144.0899@0.9676819 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 14564 1 1 1 29947 1 1 1 1 1 1 1 1 1 1 14662 1 16957 16709 1 1 1 1 1 1 17649 1 1 1 1 1 1 1 1 1 22973 1 1 1 1 1 27478 1 1 1 16294 1 1 14070 1 1 1 1 1 14951 13912 1 1 1 1 1 1 1 1 14577 1 1 1 1 1 13931 1 1 1 1 1 1 1 1 1 1 16055 1 1 1 1 1 1 1 1 15501 1 1 1 16161 1 1 1 1 1 1 1 1 14463 15531 1 1 1 1 1 1 1 1 1 17163 16582 1 1 14731 1 1 1 1 1 1 1 1 263.0987@0.9667742 1 38727 23621 1 32205 35287 32842 28131 1 35559 1 1 1 44870 38703 35861 31048 1 41773 42591 1 1 41173 45784 44798 1 1 1 1 1 1 1 21509 1 44259 42504 26277 1 30304 1 1 1 1 30823 1 34488 1 1 1 1 1 1 1 32896 1 1 28870 26408 1 31002 1 1 1 1 19911 1 1 1 1 26323 37641 39523 29321 1 1 38958 1 1 28057 28761 1 1 37694 1 1 1 1 1 30917 1 24865 1 41153 44844 1 1 1 1 42044 39263 57510 57342 1 1 39877 39235 1 1 1 27093 36124 35531 1 1 1 1 18274 1 1 1 1 1 40095 1 34332 1 1 40882 1 1 24739 27762 1 1 1 45579 40910 43920 37090 39354 50999 49407 1 1 282.1059@0.9674072 21716 13122 112977 11779 17650 18523 16938 15207 18663 17705 17065 147306 25174 23170 16974 17292 17709 20241 20833 21348 24054 26153 18131 26193 15747 22921 14492 136437 118702 12623 1 1 102799 14416 21886 12907 10622 123443 14797 14021 67362 5584 13583 15448 15595 151356 8850 8433 16068 13306 119298 122620 16423 15988 111920 1 124636 14500 17282 11445 11815 13657 153824 16900 93868 93894 18986 14816 14431 13950 22583 197812 14147 142143 1 19469 16432 15147 14254 14427 18263 10472 20556 187489 88395 8655 10774 11636 19378 15882 13343 12618 24042 24274 11564 11924 129702 124233 22950 15434 25146 18491 97936 9678 18935 18549 98337 98642 90265 125382 14287 17065 19463 21510 125738 15764 88653 8418 8988 10403 15917 163814 21992 19901 11685 16451 23567 17640 1 1 11491 109964 19993 21286 25579 25625 13066 22186 200844 19806 1 24531 1 1 HBA 1 1 33378 33995 31891 33416 1 1 18846 1 29356 29271 41215 40769 34127 34334 37746 40334 48369 1 43525 41134 1 1 29056 1 1 1 1 1 51440 55136 23765 1 30811 1 35444 40512 1 38938 1 31017 1 28185 1 29859 34216 31592 30848 33091 1 23437 1 1 52436 47422 45109 49657 1 21192 1 29927 30373 31339 20646 1 1 27094 43073 41542 32800 29982 46704 46940 46344 48145 37302 1 1 28633 1 1 43398 42813 44056 42168 70535 71432 66674 75435 25522 1 22986 23300 1 1 39338 41123 33394 37247 1 1 31978 1 30913 1 1 29706 1 1 60108 63459 64447 62085 36592 40411 42508 30166 1 1 29752 1 32770 32642 1 1 1 1 45079 49595 1 1 24095 1 1 30678 1 1 36215 36648 26604 1 45779 1 223.0869@0.96846664 1 1 19477 16394 18901 1 17537 1 22658 23963 16657 17659 24982 25008 21890 22011 21773 18989 26066 25800 1 25436 20698 22862 25387 26259 1 18557 17563 1 1 1 15611 18054 26799 24880 1 14156 1 1 1 1 18123 20471 16756 17254 1 10090 1 1 18709 18470 21110 20546 16871 17650 15878 1 1 1 17158 19808 1 22558 1 1 1 1 15857 14859 20589 1 18717 1 27394 25408 1 20849 16591 1 19762 19411 21068 21492 1 13577 1 14432 18242 1 1 1 1 1 1 1 20006 17896 29736 25069 24663 1 13210 1 19311 18761 16211 14442 1 19098 15547 1 22825 19835 1 17506 1 13388 1 1 18171 1 20085 1 19554 1 20821 1 1 1 17332 1 22536 23455 22020 23138 23415 21203 21503 18524 22466 23974 32960 1 308.1219@0.9761538 98566 100905 100577 96800 88298 90008 144942 153696 179320 189832 10559 12163 1 1 79031 82003 32936 36029 1 1 125181 122790 18291 53869 68381 86732 45641 44321 143399 135252 199849 210707 87550 137305 77971 73140 82415 83557 96436 103413 21855 21064 74951 79636 98951 97914 151256 157691 19977 18733 162321 163947 213189 229044 150775 157310 143901 99529 141507 136884 52845 51338 1 1 55318 55561 20660 21388 18888 19588 79659 74752 85253 87667 127300 123882 133925 137037 110341 119420 45526 45464 60348 63242 128462 90645 30330 27508 57731 57731 74365 77931 31774 32876 148951 151252 304032 311426 252480 259629 80885 90935 155190 162268 21285 23785 133396 122621 124980 166387 1 1 1 1 21719 21049 169934 184220 1 1 61277 61453 1 1 140303 159057 81736 46651 132513 111461 195828 200890 69185 62665 39729 38071 84484 80144 95335 72363 69200 20089 70600 61884 Tetrahydropalmatine 13229 13701 57051 56084 48275 51852 57328 58888 39203 40717 63333 64061 33047 33875 38565 40110 55815 55859 38621 40955 58813 59748 34990 36016 35658 34935 42886 41032 73185 72797 1 1 52745 53185 38458 37756 66239 68555 63902 66077 72241 70356 44807 45246 62331 62513 75827 76378 52580 53303 36457 35349 40757 44651 75877 78394 78760 79424 21346 21201 44040 42148 32584 34368 55021 57989 39336 39017 63073 63468 73049 79065 68421 68662 40212 41578 55574 57655 53305 51885 19431 18126 53906 46737 67605 66749 69369 66779 38674 38829 45847 44006 33866 34904 34190 34966 64865 61793 38733 33522 32253 31029 86501 89791 66633 69292 60339 61589 39462 47036 77562 79020 51195 52690 55822 58934 73436 72501 62237 60958 49898 50332 42836 42164 26776 27473 28722 28804 1 1 35384 36003 19632 21631 23537 21755 24114 24780 37151 37760 30642 31994 1 1 290.1113@0.97928584 1 1 1 1 3345 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 8088 10561 1 5742 1 1 3580 4263 1 1 1 1 1 1 1 1 1 1 1 1 1 8574 1 10206 13037 1 1 1 1 1 6165 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 4308 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 7022 7965 13165 18398 10688 1 1 1 10222 7459 1 1 1 1 1 8732 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 6280 8808 1 1 1 1 1 1 1 1 1 1 1 1 1 2-Amino-3-methyl-1-butanol 282386 279085 813274 791914 775921 795141 438847 645189 532023 528466 603295 605142 527628 535858 871488 875257 664058 653930 449392 456802 621528 525940 756292 771872 595966 586454 655895 594638 831525 837135 598348 614640 634970 620594 515493 523169 587081 619735 623318 623734 903277 861428 918616 923870 458696 439464 546763 574181 394433 384184 558018 577107 499080 533639 590549 563492 577083 600179 312503 311321 699365 699208 498071 528218 686415 696085 544464 538768 575612 605301 526044 527676 765519 771056 880763 984226 830593 817634 700527 700742 475634 212936 475953 473340 534261 548946 575525 477397 550868 550585 561157 501684 579561 578513 757795 741370 578856 574498 543424 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51021 67898 66619 59028 62189 55658 51816 70812 75347 1 36608 41239 45608 46500 43672 36918 36952 42252 44453 50380 55282 50644 52435 L-Valine 1800268 1799559 3194833 3208037 2837602 2896345 3281520 3269955 2363303 2421108 3696400 3712401 2379589 2181048 2498643 2495515 3946060 3893636 3433823 3478403 3940031 3906535 2924249 2902295 2900978 2858357 2285767 2496813 4273210 4288160 2971306 3026666 3028768 3017854 2813870 2819733 3619425 3618610 3823165 3843804 3473302 3437849 2848847 2863939 2882477 2906867 3547918 3607725 2422435 2422489 2152594 2195592 2281346 2308757 4917231 4926975 4822932 4842762 1618639 1626926 2458024 2504671 2314848 2087623 2430262 2434814 2349690 2398303 3013162 3038338 5108587 5113527 3786396 3746418 3125293 3113595 3355039 3359300 2933749 2942887 1023446 1046824 3654461 3622381 3722773 3703377 3486057 3458436 2739531 2679970 2238880 2493029 2504514 2492940 1853332 1835757 3888360 3827696 3057070 3010882 2511389 2602993 4822245 4787612 4566840 4579206 3649131 3633348 2711166 3035800 3960005 4048139 4402139 4378671 3054974 3123440 3602615 3606676 3694396 3712121 2926240 2920000 3206653 3228386 1924498 1918006 2082255 2102184 5544257 5669062 2021882 1944592 1691221 1718033 1844269 1776382 1849608 1928908 2874944 2886012 2752035 2779617 1825640 1876936 Urea 259876 144858 479901 498312 430875 486881 115601 125781 295569 287645 335398 354568 429630 447106 521894 410255 524544 540681 479974 482507 282746 275007 436985 418081 415568 419671 576133 582163 557012 513902 464499 471941 491666 459391 455062 502910 326993 307668 369152 417752 517248 515010 559424 567958 306556 308882 326546 328388 268817 151071 408944 536132 326698 328814 552620 563805 652403 654681 1 126092 643844 646572 596316 598601 370959 384227 288275 316824 324296 318305 263923 153990 384951 335057 350567 349609 412819 411077 501834 471837 312429 350941 365641 388937 361071 378253 414862 403989 468411 482314 413973 376998 333151 343010 522492 524855 208363 123046 133025 126183 159232 159072 397272 393814 374156 344896 414220 416044 132313 303027 354593 349787 324204 359262 153324 268401 391346 393488 291785 517222 397688 377697 431145 416904 429866 407951 479162 444674 332746 323781 471392 488517 515287 490212 360394 366695 395868 389372 414139 377813 315929 336748 417948 431798 216.0751@0.9946873 302707 288890 210849 215552 273235 274904 264763 280431 265109 271946 513718 454284 236484 235485 240845 246041 215320 220494 193201 192735 497309 489106 214146 223677 209489 211763 194913 195042 223750 218389 31339 52816 200691 203981 213389 207902 228619 237969 240639 242300 227886 223431 238738 227407 222552 229145 260123 278268 280024 293328 207290 201439 293601 295316 218685 225600 215449 223331 320794 327727 217714 225420 194893 210312 273044 266069 297185 275584 219483 212579 194252 197695 244480 253557 215218 202357 230877 230066 234149 229429 212190 209926 192647 190973 221273 220144 255721 245589 202379 190100 156640 146711 246726 244058 201877 206510 232429 234327 208866 207399 492831 487561 249036 242562 282321 292812 207097 205101 189475 214414 281145 286086 189479 190417 432437 448100 219307 211874 175939 179958 256576 245698 221469 211576 206090 212321 200738 195018 68220 72140 227757 230053 224756 220281 215949 221606 205099 201960 230256 216468 233958 230300 77510 78739 278.1845@1.0056154 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 6453 1 1 6653 1 1 5248 1 5729 1 1 1 1 1 1 9094 7866 1 5996 1 1 8116 8551 7904 8930 1 1 1 1 1 1 1 1 1 1 1 1 7807 1 8530 1 1 1 1 1 1 1 1 1 1 1 10271 9180 1 1 1 8244 1 1 1 7552 1 1 1 1 1 1 1 10119 9356 8348 1 1 1 1 1 1 1 1 1 1 1 1 1 1 9188 1 1 1 1 7353 7328 1 1 6769 1 6793 1 4511 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 344.1333@1.006892 8753 1 33781 36431 43546 42680 10793 12237 9479 10109 20862 20812 1 1 1 8343 15899 18193 9462 12072 34288 33246 6713 8901 1 1 1 8366 11381 11502 1 1 20751 19896 15088 15228 22330 23550 16666 16361 12164 12586 1 8814 23043 23227 14645 12115 19659 21696 16250 18117 21829 23614 17653 19420 21778 20813 8364 8301 16566 17195 12892 11338 14771 16180 10408 10776 11623 10698 24664 26265 29652 30557 15008 16095 23611 23654 21846 23349 1 1 1 1 9675 10629 1 7521 1 1 18508 19724 1 8445 7625 9587 17921 18790 10540 11807 24947 28062 22194 21544 15105 15985 9472 9419 1 1 1 14781 1 1 17332 16828 26259 26212 14364 15602 17825 16554 12617 12001 1 5224 1 1 1 1 7297 1 1 1 10639 10926 10706 10597 1 5901 1 5426 6101 6096 337.148@1.0104705 1 1 1 1 1 1 1 1 8530 7197 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 9042 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 10145 11169 15319 16195 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 8538 14215 15165 12257 14060 1 1 1 1 1 1 1 1 1 7538 1 1 1 1 1 1 1 11396 1 1 1 1 1 1 1 1 1 1 1 1 9764 8611 1 1 1 1 1 1 1 4641 1 1 1 1 366.1571@1.0097522 1 1 135520 127361 128095 115092 44960 41365 26469 26645 39526 36064 16580 14848 21930 19274 52527 52496 32292 33412 65982 66519 25938 27835 19317 19195 29336 28378 38834 36988 1 1 85185 79590 50789 51012 82050 83644 48736 47023 49429 1 27024 1 96297 98285 46846 46198 69796 60905 52366 55899 65777 63140 46491 46998 61335 61917 15608 14575 53042 47461 35067 33705 58168 57097 25637 26432 38376 35627 85047 87616 86747 87844 43191 42561 72241 67431 67259 64610 17464 18101 21822 23233 31516 29407 22060 21782 11746 10318 66832 66033 20981 21573 25811 24457 59234 51860 32647 33168 36823 34185 59158 55222 31982 31992 21801 20309 24272 25763 48675 46744 23952 22510 33938 37780 104569 78085 52577 50139 51404 48315 37073 34852 15036 13144 14293 13284 1 1 23160 19990 11369 1 32440 32896 36363 34112 16877 17902 16760 12810 1 1 128.0584@1.0091015 163874 162339 529311 521048 554521 561574 145677 148412 132505 134942 183567 188832 103789 100976 111586 110242 289548 284691 240304 241252 376178 384464 157176 165860 136488 133542 140411 134868 1 157441 53742 47989 335054 339168 328166 322837 319368 323603 234903 230271 158864 155660 132112 131304 317789 332486 153136 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4335009 4336438 4586194 4609982 4787125 4817860 3898963 3909159 4574458 4712582 5409825 5403408 6235567 6228295 3786355 3828987 6144228 6198530 6353087 6458866 6153086 6158691 4463797 4501938 9132645 9145123 4373310 4365236 7763724 7742083 8530820 8476722 8054242 7966427 8208902 8219691 3551120 3588261 7461925 7594943 7927248 7930869 7592442 7660016 7686955 7614360 4913270 4926775 4384981 4368815 5231225 5217001 5116799 5096402 6408520 6507355 4446793 4457862 5294417 5225950 4739651 4727845 5976101 6070591 5816006 6813454 5647085 5707101 5861147 5804620 4685310 4756956 4591416 4604092 4227524 4209097 5655883 5641924 5471531 5397573 5637273 5580559 5329532 5330678 3911547 3927720 5651197 5638331 6004957 5889015 5867885 5867841 6373191 6391327 6763312 6793253 5942826 6034826 4049909 3998205 2-Oxo-10-methylthiodecanoic acid 25546 23896 11676 11537 23324 21311 17579 19690 19731 19186 27234 30104 14599 1 12438 12107 15841 15306 11585 11966 34798 34036 17870 16667 15051 15041 1 11901 1 1 1 1 17825 17046 15718 17353 27049 24304 24104 22846 23238 23858 28436 28987 22669 24694 29636 29391 16697 18966 18351 14590 23112 24464 16550 17618 21579 20083 42732 39423 13563 1 18901 20066 21725 23003 18897 17378 13614 12661 1 15182 18202 19361 13629 14788 14137 1 16300 15888 12727 13537 13706 14658 1 12587 1 1 1 1 13238 1 18699 18584 12288 11350 18434 17876 15364 15465 29192 32395 17846 16043 25516 24410 12694 1 1 1 15788 1 12502 9996 17536 17807 1 1 1 1 15724 14766 14060 13909 16709 16306 12382 1 1 1 20568 20949 16652 16060 18844 19883 12515 1 14991 14125 18835 17325 1 1 103.0632@1.0309334 1 1 1 1 1 1 1 1 1 1 1 1 1 1 21423 1 1 16719 1 1 1 1 1 1 1 1 1 1 1 1 1 1 19747 19983 1 1 1 1 1 1 23056 1 1 1 1 1 1 1 1 1 20829 1 1 1 14944 14851 1 1 1 1 1 14413 1 1 1 1 1 1 1 1 1 1 1 1 1 1 11669 1 1 1 1 1 22449 1 1 1 1 1 1 1 1 1 1 1 1 1 13057 14146 1 1 1 1 1 1 1 1 1 24370 1 1 1 1 1 1 1 1 1 1 1 1 1 26635 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 3-Pyridylacetic acid 1 4611 77505 102060 112818 111544 59015 51983 57979 66178 52801 31009 19556 29658 1 1 149742 154800 85292 88783 21848 28310 1 15039 37793 47360 19949 20363 20904 21194 1 1 121986 118518 138038 140549 29723 27169 38601 33154 26186 27273 13392 1 1 22699 384703 380088 119791 118775 157849 150612 198861 187550 182229 179368 333841 339759 1 25187 173033 179822 157247 153746 1 1 17494 18370 23211 16057 41081 40751 1 42144 67962 70706 121683 106841 43140 1 1 1 119902 112138 79857 82390 52360 50139 87597 67575 64810 60980 81627 84770 68534 64127 153205 159164 129462 133340 36731 26979 29055 30137 27885 1 115971 118729 57560 57607 175747 176146 119062 111955 113242 113064 66619 64914 189797 191106 28552 26836 52924 45259 30069 24889 59708 61906 27147 36087 29466 35600 1 22591 62810 62241 130453 127406 58906 60275 96727 96530 69998 63448 N6-Acetyl-N6-hydroxy-L-lysine 53450 51375 67376 67985 350981 375882 190457 194190 235475 231113 103391 105934 170247 159439 180017 178797 223743 233931 117984 126922 59171 60879 188161 188451 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1280570 1601810 1601809 1078781 1055884 1400569 1448200 1452252 1460844 1245076 1289134 952576 1231842 1119749 1353995 1108203 1279201 1304560 1362607 1295125 1318343 1218119 1325188 2035751 2040764 1009265 1327554 1217687 1275643 1466772 1210022 1199223 1292287 1165991 1171599 1392075 1386626 1878998 1852158 1197620 1151976 1458311 1513301 1291091 1306673 977595 1038230 1114318 1106048 877820 865987 911442 919753 962681 972990 959019 982513 990358 996898 1027590 1052675 807176 969205 1064786 1028492 1004632 1008674 1457068 1422811 1058167 1037907 953481 915461 1004872 1030774 852215 845566 969632 964884 1201519 1207092 1045951 1043481 3.09E+07 1255494 1466686 1589770 1549067 1503903 1513330 1467036 1139231 1142681 1499237 1505489 1106014 1129150 1561772 1595724 872657 1045887 1238428 1242863 748254 930906 845873 839311 1025467 995919 1208457 1277940 1214977 1046581 1212455 1230787 1234090 1255447 1216920 1220687 99.1047@1.3450768 1 1 1 1 1 1 1 1 11429 11057 1 13889 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 11978 13492 10895 1 1 1 1 1 1 1 1 1 1 1 1 1 11966 1 1 1 1 1 1 12347 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 8540 1 1 1 1 1 1 1 1 1 1 7509 1 1 1 1 1 1 1 1 1 1 1 1 267428 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 7739 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 10019 1 2-oxo-3-methylvaleric acid 1 1 26186 28769 33683 1 1 21294 22507 1 1 18848 21488 28763 26725 24387 18714 1 19575 19934 18788 17993 21398 22845 19965 20077 24977 24594 26306 25463 22467 25530 16393 1 21475 14525 1 19587 19911 1 32236 32216 27066 26869 15725 1 25021 29039 21815 1 22475 27419 23574 25360 22100 24278 27344 25406 1 1 30278 26426 1 23275 1 19826 1 32372 20744 17941 19319 1 18515 21404 25077 27648 27029 31082 1 1 17580 1 19279 23099 21087 22781 1 21796 1 21068 15098 16088 23451 23352 16646 17827 25463 29295 27017 10967 19889 17334 25110 22708 1 24869 23750 19707 1 20184 18746 19434 19199 21664 22261 25839 26536 29114 23980 1 31814 32010 27669 28846 1 18141 22963 24098 1 17607 27182 24738 23914 24122 20415 21223 1 22437 22359 27202 22972 20921 1 1 Uridine 6141 1 18272 1 15412 16725 11335 10622 11269 12968 13353 1 1 13038 15034 1 16485 16628 14522 12324 1 15734 12069 12901 13313 13504 1 13547 14075 14570 9731 8739 16233 14264 14783 15301 1 9646 9097 10662 1 1 13961 13538 15508 15602 13676 14605 16693 14664 13419 14738 14567 15721 14779 15077 14010 15331 6732 7670 17873 16918 19234 17168 16106 14525 12290 11013 12438 12219 12604 13064 20165 20232 18089 17558 18258 18738 20175 19318 16707 15249 12147 13960 14675 14409 14879 1 12460 11136 13885 11876 14048 14103 13643 13599 15401 13626 14870 15569 12253 14170 10705 1 9511 1 13220 12642 15304 14885 14771 17175 16504 17072 11607 11769 17666 18543 19646 16397 1 13958 16006 14275 14459 14364 12709 12424 14954 14350 13119 13839 11997 13078 15960 15907 14773 15881 13849 14308 12048 11924 14008 12645 129.0788@1.3696271 1 1 1 1 1 1 1 1 1 1 87909 98418 47521 49679 11335 14747 17015 21717 31671 162801 22560 119912 1 11954 138917 1 1 1 11599 1 1 1 39568 46656 23283 25038 1 18955 1 1 1 1 1 1 1 1 1 103249 1 1 40511 1 22840 27743 1 13042 1 1 1 1 36447 37402 75268 85742 1 1 1 1 89224 80745 1 1 155859 1 1 1 15696 1 18249 19524 60343 59409 1 1 56701 52104 1 1 1 18895 53035 43452 1 1 1 22441 1 1 1 19391 51245 50785 1 1 21441 20085 15280 27655 1 1 1 1 1 1 1 16183 1 1 1 1 1 1 13683 1 1 11534 1 1 1 1 1 1 1 1 1 1 223796 10765 159614 157488 1 1 45632 55359 DL-2-Aminooctanoic acid 63894 61275 86452 95909 80428 79178 63592 66657 83228 79432 64788 70599 98573 98815 123918 125178 71403 51636 81807 81854 50698 46828 134937 143001 133488 129670 106524 98339 104760 102540 108125 107902 105006 104201 108092 108446 60785 57255 54772 55119 43139 40783 1 40052 57219 54981 140615 131985 116698 119706 58279 59223 90981 88470 82387 79160 92533 94866 93556 89042 103747 100238 97458 99886 87312 84585 71451 70425 92433 92656 46429 47821 103431 100539 142970 140286 182571 185431 141378 141655 54020 53370 108097 103986 111084 112584 214709 209324 216933 224728 62365 60916 94099 99210 113614 111148 85209 72606 86528 89824 70077 70535 67026 69581 54617 51097 134907 131945 127661 135054 73380 72402 80587 82198 83967 83529 81307 85052 76200 75281 73173 76576 77541 78922 104307 110801 110704 110538 19280 19046 119656 113270 117974 120764 154365 152282 156160 155626 107042 104398 83856 83676 97219 100291 143.0947@1.3826578 52153 54524 35756 38636 29104 34883 48969 48939 55363 59690 21387 24373 9515 1 1 1 100130 96338 81303 83774 75497 82688 83368 83690 87888 81257 64025 59881 58976 63419 1 1 14878 16646 17499 21694 1 1 1 1 1 12509 1 1 49210 46521 69780 68074 56406 59451 22198 23857 29083 25395 29264 1 16634 38659 1 32680 138593 143731 102267 105286 17545 15611 1 1 1 1 65069 60026 71510 76769 72161 71572 63592 65423 59268 64925 63391 66080 22611 1 1 26363 1 11648 1 1 40514 39952 50055 53499 68547 65726 16628 16089 15520 1 36267 36731 42335 36962 31894 34592 58721 57223 44783 55113 22916 20265 18899 1 1 1 14838 16074 26934 25981 44460 49830 59849 57168 81721 82832 83461 81467 1 17314 66235 71034 67441 63051 1 14895 15724 1 63209 61792 53442 56362 15554 15778 216.1224@1.3916757 1 1 1 1 1 1 1 1 1 7836 1 1 1 8459 13430 1 1 1 1 1 1 1 1 1 8114 1 9266 1 1 1 1 1 16105 16264 14937 16962 1 1 1 11608 1 1 9514 10674 11245 12260 1 1 1 1 1 1 1 1 1 10369 14570 14102 1 1 1 1 1 1 1 1 1 1 9783 1 1 1 10420 1 13236 13785 1 1 1 5324 13251 12655 1 1 1 12601 1 9972 1 1 1 1 1 1 14658 1 1 1 1 1 1 12121 1 1 7774 1 11035 10821 1 1 8929 1 1 1 1 1 1 1 11834 1 11574 1 1 14291 1 1 1 1 1 1 1 11153 1 11310 1 1 1 1 1 1 1 1 1 1 Uric acid 1 25402 65570 71204 71569 77519 43705 45148 44886 47311 48419 47769 53738 52266 53896 58447 66861 65204 65876 65240 54069 51625 56011 49222 52205 51706 54056 58257 54365 56696 58293 56762 56403 61633 66804 70641 55229 56830 59766 57739 48932 49188 57420 55615 71695 68082 54344 57682 58085 60070 45247 50808 37076 39699 64197 66288 74388 81872 31237 32501 59940 61805 55525 54899 62115 60844 43826 48340 63817 67742 53729 51541 71459 78920 68784 70765 65003 71028 69454 65241 54186 52480 64749 70461 66430 65664 37049 36860 37590 37350 52626 45758 44105 43465 41075 40629 43174 42919 45914 50764 38440 42742 27785 30758 34543 33654 53432 58529 44279 54990 31969 35681 37801 37376 35680 33833 60619 56870 54643 54278 61347 62634 61347 64967 32839 33397 35578 35298 30326 31468 43925 51954 50237 47783 40657 43090 45143 45770 46000 44011 41148 41933 21163 1 168.0789@1.4007142 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 70501 1 5004 1 1 1 1 1 1 1 1 1 1 1 1 91037 1 1 1 1 1 1 1 1 1 75124 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 90192 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 53217 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 55942 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 138.043@1.4048334 1 1 1 20874 24696 1 37954 36672 52665 55444 1 1 1 1 22931 1 11016 1 1 16542 11920 1 1 1 23393 25189 18750 18800 1 14819 1 20298 10688 1 17966 18966 1 1 1 17505 1 1 28468 27240 1 1 1 1 1 1 11461 1 1 1 1 1 1 1 1 1 1 19061 1 1 1 18318 26494 25559 1 1 1 1 1 1 1 1 1 1 1 1 50223 48294 1 1 1 1 1 1 1 1 1 21302 1 1 1 1 1 1 1 1 1 1 13098 1 1 1 1 21850 10683 1 35660 35753 130608 131285 1 1 1 1 1 1 1 1 13596 13530 14885 17440 21574 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 157.1105@1.40279 1 6788 9347 1 12583 11666 1 1 1 1 15948 13956 17754 19009 1 1 17193 15428 19798 18899 1 1 17249 20328 9753 1 24158 27017 21508 21722 47132 45513 11592 1 21285 1 1 1 1 1 1 1 1 1 1 13133 31925 33108 11446 13037 13215 1 12891 1 1 1 7804 1 17189 18334 1 11515 1 1 3183 1 1 1 1 1 1 1 1 1 1 9438 21928 22747 13863 13279 10354 1 1 15974 1 9492 1 1 1 13316 1 1 13692 12966 1 13122 13807 14471 16886 15050 1 14586 8700 1 1 1 12407 1 1 1 46312 53335 37362 40917 40863 39787 27605 30903 14028 1 5347 1 9403 8599 18777 20729 22588 22238 14819 15095 1 7704 1 1 34663 32543 15798 17369 43416 40649 29626 29290 1 1 279.1321@1.4038168 286736 363326 434003 432889 424284 438586 267361 256225 408602 418214 47861 42344 56237 45896 444173 451534 173858 167163 17539 17458 465094 467824 256535 308708 407360 420400 183696 190038 513705 506637 835861 819893 609183 574413 397050 407395 306935 338500 451611 425369 101873 100204 523745 434435 356106 361870 329220 411711 31610 42676 662971 654848 599175 655466 693112 721080 952393 780489 362715 372712 254230 213965 1 6521 284955 238568 106892 111931 84956 81513 271229 276533 296404 311557 486036 387021 687900 713634 681909 694163 160033 155760 463136 466230 455470 452747 144985 149762 408487 386354 269094 258370 95483 99356 480708 480321 566418 561094 668210 656571 451122 461230 475159 455715 91598 72407 497031 524014 267718 418758 1 25492 34351 34369 44332 45336 433747 552735 12735 12278 237708 282474 37386 40476 562316 561308 407353 407607 476263 459541 868501 880273 644331 663008 149309 148653 282118 285264 492053 523119 411305 345164 297525 308884 DL-pipecolic acid 97616 96975 226693 225631 221102 255556 156778 155981 182290 103463 180509 176043 206277 209907 141038 142883 150929 140696 157015 1 99223 1 146201 140376 1 135520 156083 142194 144730 141700 122581 113680 154289 157398 143475 142102 292956 281444 253318 252324 206755 189018 159965 143351 108637 118520 190082 181602 177211 207767 222248 224750 211632 223178 535396 556857 389364 396987 80797 78288 177017 179504 181410 172128 84001 78581 77281 60437 1 1 276201 244021 1 158395 135635 146817 143573 145037 138031 147314 116893 118051 81679 86170 100681 1 186049 202306 184389 176813 116537 125146 158094 170115 119601 117701 275945 276942 265283 281191 105056 113198 120216 123335 118464 125424 151880 151227 100806 152972 186799 193108 209377 215535 124538 108809 174020 191832 207995 175031 149444 153308 146702 157044 90229 91443 100524 109699 149431 154029 157376 161549 157131 173042 193665 212978 1 211645 1 1 166212 154949 1 96594 THTC 78762 80523 142299 149166 153980 165578 130154 135032 129680 133942 205371 209599 147489 146843 141099 136171 174266 176257 164675 171000 181257 174014 149956 149491 124279 130026 156540 153005 145482 151436 155750 154017 116953 116887 160236 161567 181406 176991 171611 167168 190785 197414 139316 139611 163233 168550 109321 112260 128600 130435 116394 114344 111027 114127 101952 108250 117563 104286 111713 112455 170359 174624 164118 169439 188056 189334 140865 140639 175268 177968 178982 185128 142811 145000 163490 167733 118250 119037 123098 130165 146694 148571 143507 146676 164748 163864 151214 155648 134054 132010 168471 163585 150042 160315 119707 124084 116416 118542 123929 121883 192560 198308 139695 138089 174703 173559 121433 127208 78991 129388 165769 169281 164295 170903 259158 266256 134514 141130 156864 159980 152479 150317 170467 173743 129564 126443 143826 136493 170634 171695 95670 91935 102470 104313 1 153119 118075 117208 109388 107340 107273 101738 121618 119392 L-Glutamic acid n-butyl ester 568683 566588 1522524 1532164 1754075 1800082 1352271 1364367 1052396 1039740 1088829 1067163 1601021 1579730 1545912 1539703 955879 937743 1118261 1108497 921078 924485 1233142 1223513 960491 966204 1472552 1433365 1487397 1481012 1445169 1412587 1472095 1497049 1709562 1717834 1404272 1381480 1049687 920401 1021138 1022729 1614600 1595496 628446 638368 1717383 1709598 1197595 1204655 972845 976079 883770 908161 1435497 1445346 1677450 1679574 438887 427313 1827149 1786682 1875748 1834065 1056803 1072831 1135395 1124879 912206 906027 843859 845249 1794177 1862490 2160064 2166697 1503245 1480391 1611961 1619890 888953 905530 2209131 2220415 1782845 1800863 1984432 1964801 1255072 1208557 723395 747585 1007422 1001235 810146 803125 1470215 1473671 1302913 1313237 566079 578709 1240533 1218188 1297132 1280531 1988485 2036636 1279253 1526640 1122261 1145913 1155277 1167202 879286 877376 1863917 1853258 1179316 1178639 1847993 1836241 1581118 1575520 1650695 1544051 1861498 1831358 1011380 1008256 983969 996276 1203175 1189518 1230955 1231125 853723 856636 1574710 1579032 1480211 1484810 430693 421919 4-Oxoproline 31147 33080 43239 45088 38848 36970 56473 62086 73492 78723 58066 49595 44954 47894 39737 37232 57784 48413 51501 53626 53398 52114 65031 69308 45571 50470 60120 63703 44050 46037 55320 54567 41909 44746 58474 58655 48618 50269 48446 41054 73165 68109 67823 64894 56062 53831 42767 42537 69441 66728 42961 47637 52641 53312 41564 47448 1 55369 33429 37208 51176 60323 62791 61914 49739 53216 47628 47096 58342 58386 59773 58531 53818 57121 62615 61601 44765 42722 52493 52113 82001 83786 44211 44984 43770 45571 62509 65627 61604 59848 75642 67587 83614 76492 59383 59848 59248 59073 57480 55595 47129 51145 55581 54758 73636 82247 46127 51192 30803 47416 62584 71969 104754 103939 196762 185787 52639 47609 101420 99680 63877 67803 88069 92651 40568 43163 59100 63417 86611 99049 39787 41127 44849 43841 47210 47886 57747 56269 35258 37026 46606 42310 169597 170358 228.1478@1.4183953 1 1 22054 22124 24255 24965 12698 13909 14682 14661 14113 13793 1 14400 11804 15545 26993 24255 21758 20883 21424 21853 19620 18383 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1 15838 1 332841 312028 63214 60154 1 1 15947 22104 239073 230441 1 1 1 1 41454 40129 32757 35188 1 1 19572 1 33937 33886 1 1 1 1 1 1 32860 1 416172 444710 14930 1 1 1 17043 1 1 58481 1 18931 17404 1 41092 39508 1 1 1 1 20485 1 1 1 1 1 24190 1 79802 75437 N,N-Diethylglycine 59981 56653 75273 63122 75374 74015 68278 71167 72621 65322 74076 75958 67523 70281 73039 75764 47753 49677 40085 38877 36211 40631 40736 41934 30557 1 20360 33574 42422 46159 91496 82868 77592 55381 79979 81733 89850 91373 100544 109051 73108 76824 79363 84835 1 72147 67519 61304 105251 107406 64614 64582 39762 34777 44422 44644 55754 61314 1 1 94619 96910 121982 121063 89360 97404 126505 123966 90481 82770 1 1 39255 41861 40039 36361 37767 38819 50282 45989 35106 34780 45874 41495 34912 23184 1 1 29859 38671 41849 1 38784 40323 36105 41316 41437 43861 52556 48452 40372 42510 39604 38851 40041 34957 44185 37162 79018 48046 52272 57150 48839 1 41848 46020 53063 51034 61627 62396 32446 32430 66250 64487 41183 42222 52812 54240 43200 47188 49314 47983 43156 39481 71564 72805 67187 63062 58977 63313 62724 68818 58925 63631 180.0651@3.6668572 35920 32228 16565 12955 1 1 23353 22575 42588 46285 65939 63445 16620 16161 1 14202 21790 1 23546 23041 133372 134023 1 1 1 1 1 1 34176 35538 26507 25166 58054 51944 106168 108463 117238 119244 102057 98556 61456 59903 60417 57428 1 1 41622 40454 24264 22453 189739 196679 125408 125544 180629 189902 192000 195649 31685 27513 108138 112372 32194 34946 19032 20268 25084 26636 1 1 1 1 133834 132276 109151 108988 35162 34656 98310 102593 1 1 57099 57262 64729 71038 93296 89153 16216 16246 1 1 61540 65009 32958 32584 81241 82263 64022 60266 55512 53145 1 1 1 1 29716 26636 28938 28092 29632 31417 49020 49199 90639 94254 22954 23265 23142 22801 1 1 1 1 38840 41607 40810 45967 1 1 30398 35303 1 1 33244 31229 91846 86052 17491 18444 47929 46304 130427 131427 194.1157@3.7127526 130297 128747 163007 47666 130228 217675 115300 168060 148937 149300 133986 131094 146225 132159 43533 89286 142322 116122 33292 1 87652 124020 127610 92282 71090 123495 1 83857 51395 152977 114685 133498 121713 136861 76994 89207 1 1 1 131602 117470 125539 1 1 96841 121182 83641 149023 85894 134013 108317 79662 1 144441 105127 1 98788 93858 1 77887 101270 1 106066 132826 1 1 1 52350 1 1 129768 112632 1 123078 42047 1 1 1 122144 135890 147883 139172 30746 45114 50893 1 132248 133857 54583 1 102975 102944 1 123816 1 105236 1 94730 121055 1 32704 129563 94396 1 1 91523 1 1 276260 135925 51678 90919 132857 120550 1 97310 1 1 59579 118999 124798 97166 118154 1 143563 126844 42640 25781 125734 174188 140606 116443 124489 118011 44925 130779 113681 141653 79804 1 124672 83556 121145 177309 Diethyl Oxalpropionate 1 1 1 1 11038 1 20944 20527 1 1 1 1 1 1 38406 37332 1 1 1 1 1 1 1 1 1 1 1 1 20754 20951 11861 13140 25700 22082 1 1 1 1 1 1 1 1 15258 17200 1 1 37036 32323 1 1 25458 22296 17411 16852 26450 28085 26523 24160 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 14288 23855 1 24614 24834 12042 14532 1 1 35292 32429 24478 26226 1 1 1 1 1 1 1 1 1 1 10182 1 18917 18333 1 1 1 13438 1 1 62698 54005 20018 19014 1 1 1 1 1 1 17156 15003 1 1 18800 18076 1 1 17907 17182 24770 24389 1 1 1 16420 14947 16180 1 1 1 1 26237 21748 27533 25402 1 1 o-Methyldopamine (3-methoxytyramine) 14928 1 58956 55053 41468 47661 1 52610 64495 62259 48717 50713 96853 97412 78835 75561 49557 50929 48037 50380 32836 34514 37531 40446 43094 43662 72029 69494 65921 64985 31941 27286 38041 35479 54352 52796 42416 42259 43844 41259 52489 46550 51834 51932 71894 75152 50667 47171 52005 52204 59607 56630 60190 58108 81318 85992 100322 98406 24324 25778 59623 59076 87061 89999 39457 53993 37155 38430 80075 77712 73155 72652 34253 35847 37267 36508 29763 1 40270 42201 35935 32667 44573 49594 1 32373 52135 52955 47793 48545 42668 39967 51251 51563 32983 32073 69847 70154 69724 70675 43860 41096 26135 23817 26277 25527 58131 58228 71395 71433 70372 73188 68532 67360 32277 34072 64360 64430 53940 57909 53198 55613 54641 51426 52197 54849 62280 64105 41117 39621 70083 73076 77147 76144 39155 40361 43329 44296 42692 41351 49720 54789 18150 1 366.1424@3.9333456 37710 38200 28484 25333 1 34829 22685 11485 40878 1 1 1 1 1 32289 34840 1 1 1 1 54259 57426 29754 30446 42953 42264 1 7543 36326 33683 38035 36411 32996 30887 21077 1 22521 21651 35293 35037 1 1 29871 28511 29682 28430 31416 30863 1 1 49065 50717 69279 74535 65976 67730 70273 77525 32853 32170 16412 18654 1 1 12487 1 1 1 1 1 33486 19430 28964 13535 44784 45622 40859 40731 51453 53215 9938 9924 34647 34537 28482 15599 1 7546 22735 1 23023 22430 7965 8103 50151 48457 56517 58416 46519 52751 68685 73422 55358 20428 1 1 37549 37616 49446 51139 1 1 1 1 1 1 52959 56529 1 1 13865 18169 1 1 42634 64095 35425 33723 22223 21162 48051 47377 32673 30726 11745 1 44997 46772 23479 1 44996 44583 12298 1 231.1473@3.9387593 1 7072 56240 57266 33916 35970 14930 16282 14985 17500 29107 31401 29438 29094 30182 29297 32998 35064 46271 43678 1 1 26883 27296 26545 27145 18459 18519 24521 23703 41678 42561 44749 41103 35700 37685 22574 24084 15584 19943 38110 38352 28885 28019 14845 1 23589 1 14862 13703 17134 16053 12631 13090 50196 53686 60118 60819 1 1 54461 53630 48563 48260 21702 23743 12118 13676 36799 39970 20841 22900 21939 22226 19432 19508 21594 24254 18196 1 1 1 39415 35395 29840 31560 38108 37783 47623 47449 29591 29751 25155 24794 43338 45160 21724 22223 26885 27449 31180 30516 23220 23578 1 16482 29186 28267 22164 21886 20786 22388 17322 16502 25865 25334 23784 25918 18803 17085 21684 21281 21182 22072 31109 30233 32230 33997 21379 23848 54286 52554 68142 69703 18609 17086 16175 18258 41236 41425 38400 39746 35825 33693 Indoleacrylic acid 189244 189324 315765 337083 321109 332674 255358 265293 291785 322253 456875 479266 281915 299779 293250 291312 354127 349800 297902 311537 454617 459085 344107 361830 351483 349372 268609 272574 262053 269892 434943 430025 232312 238307 275600 288191 293007 300474 360405 353629 282192 294202 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83846 86176 16495 18593 71498 67676 65841 68169 1 1 1 1 70867 74279 72646 70896 126358 133876 35008 36493 1 1 197023 202708 101507 107225 61628 68193 48271 50171 1 1 87260 88837 28112 27191 120759 114052 95003 101722 1 1 1 1 1 1 81573 79713 45599 44947 83145 80396 101283 102945 103204 101738 70672 74747 36033 1 1 1 1 1 24611 24825 38135 40773 1 1 35476 33807 28123 28019 63190 65829 93143 95097 44609 48131 101406 111733 1 15141 231.1474@4.0326653 1 1 19646 18418 18177 16848 12105 13583 13618 1 13566 15613 16901 18864 19005 18814 15371 13795 17453 17932 70617 68818 26366 26434 23236 22702 15767 16417 15402 16386 23390 25393 13295 14837 13194 14640 16622 17225 12598 11288 19400 20814 23292 23939 1 12781 22902 24629 22740 22626 1 1 1 12947 19418 18828 22623 21371 14128 13962 17435 20226 21941 20724 17016 17541 12865 11362 38346 36064 11210 11604 30715 33740 39030 40302 38385 35973 37228 36758 1 1 19618 18780 21386 20801 24481 26350 29997 28839 1 1 30841 32752 35786 32343 20898 20384 25157 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82203 90012 89107 86423 86536 82574 88341 100946 246.1371@4.4644594 90507 89497 525435 533635 440456 436313 220501 227169 98731 101945 236290 233455 20290 18389 13113 14893 119834 115182 106600 103778 395424 394818 72537 73426 88041 89140 96464 93085 135429 129022 1 25637 86576 88278 23761 24121 62329 65975 68657 65710 220462 214804 323781 318745 107962 111808 224522 225396 128907 131028 64801 62735 49232 51282 219818 224349 170765 178342 31393 31836 363605 363424 491099 481817 82023 85914 32125 28414 85149 98287 360527 355844 1 1 17187 16473 885119 866823 1092918 1096798 99293 104313 85129 85358 253921 254303 23073 23535 1 5765 168051 174118 132302 125775 108747 108924 535549 530817 556554 546485 96629 97313 53343 54024 32755 33000 86881 85585 148995 153414 347029 346271 222292 225969 161395 161769 126898 129425 25424 29286 64442 63782 43767 44817 1 1 14891 1 932560 931904 45722 49811 105868 108367 121112 121266 83350 104020 97156 100601 97260 99766 252966 245161 177.1007@4.481571 1 1 16610 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 12469 1 1 1 1 1 1 1 6404 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 12355 1 1 1 1 1 1 14598 1 1 29505 24449 27459 26959 1 6509 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 17743 17079 23243 25070 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 243.1473@4.4995003 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 7108 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 8206 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 113.0839@4.504435 168436 160113 186310 175853 167200 156052 204659 214024 148636 142359 215066 189115 194862 186031 212487 196925 160844 165563 167782 181419 180609 176715 245498 249025 190258 194984 257255 252990 214259 231287 114300 120899 113061 122970 109794 88694 131029 118171 139899 136000 94853 95323 82582 83953 86897 97456 124960 115313 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1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 3-O-Methyl-myo-inositol 1 1 20032 20704 1 1 95636 89748 99868 98806 1 1 1 1 19086 1 19991 21209 1 1 38688 40489 1 1 23887 26196 1 1 1 1 100443 102024 247745 251335 160808 165545 17421 18699 50369 50105 1 1 1 1 1 1 261944 257258 52350 52445 72179 76860 338513 346474 78420 86561 429149 436806 31476 31854 140382 137517 1 16570 282768 290372 204775 202564 1 1 1 1 191895 202546 167022 165918 501511 495661 54173 50973 1 1 383344 363462 169355 174427 107882 115132 58901 60130 1 1 151819 140940 30334 31749 400919 408085 323581 318555 1 1 1 1 1 1 201582 208145 128956 126849 148364 148411 253650 248395 148342 152511 419287 436086 458019 463315 1 1 1 1 46260 44525 77204 81031 1 1 61040 57578 60188 63162 70158 65124 110229 107560 66972 63989 263798 265265 25601 26803 326.1939@4.611888 98665 95208 88433 86747 90462 88388 72790 73537 74664 73312 79894 66687 77916 69096 92572 92044 71876 74209 75514 75173 77053 78414 95515 95111 76451 76525 74350 75298 75073 72211 85813 81140 76413 76328 74103 71677 70626 77332 75303 72840 80288 79752 74531 77987 76950 75554 92394 93118 76375 76120 81880 76805 102527 107921 71615 73325 70553 70988 76064 76929 73019 73775 74500 70220 74441 75444 74025 74472 70959 76758 83135 84173 121422 122038 126786 129715 88744 81790 79093 83359 79295 86066 87647 85211 88865 82408 81933 84186 92932 93956 143163 141707 82708 86214 84703 87907 83921 1 92726 85384 89811 88193 1 84859 91558 1 88893 86372 90290 90688 84439 85212 86252 86905 83270 91851 81241 86145 82911 82239 76169 88669 88781 84420 105989 104643 81398 82625 82948 80959 1 82738 83042 84980 84851 84921 82513 86458 84220 86869 85803 82043 90528 93501 AFMK 11192 11255 29330 31545 26768 19247 1 1 14191 12133 1 1 37686 36051 60515 62899 1 9282 14233 13352 11427 11789 18735 19882 14531 14809 6431 1 17643 19142 12409 9792 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1 19938 15602 1 1 16869 1 1 1 1 1 10855 1 11890 1 9228 11404 1 1 1 9497 1 1 12652 12441 5690 7460 17000 1 14152 1 12499 9002 1 10261 1 1 12213 1 1 13155 1 1 1 1 13218 17071 16513 1 1 1 1 1 1 10798 1 1 1 104.026@4.7411995 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 12283 1 1 1 26042 1 1 1 14883 1 1 1 1 1 1 1 1 1 62051 59806 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 13053 1 1 1 1 1 1 15151 1 1 1 31434 26752 16416 16182 1 17677 36255 36687 1 1 23256 22949 1 1 1 1 1 1 1 1 1 19574 27374 29124 29777 30027 18618 23018 1 8515 20526 21717 1 1 1 1 1 1 19092 1 1 20500 1 1 1 19150 1 1 1 1 1 1 22259 1 1 1 1 1 1 17995 1 1 12475 1 1 1 46230 46163 13808 1 1 1 Hippuric acid 1 1 37536 36305 41215 39427 31672 34647 35948 32488 38536 36377 20830 19990 22975 1 58405 59146 21680 18380 50534 51763 22418 23595 42686 42664 24096 25132 85531 54221 41362 48502 54345 46466 29659 29844 32597 31989 31278 30420 26724 31697 206085 217879 24912 24407 22458 17059 49965 51893 27612 27946 36831 38983 38426 33792 52189 53932 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1 24598 19238 24546 20796 1 20622 20289 21714 14633 22499 13139 1 27542 20491 22974 22422 22882 11809 19896 21016 19827 1 19714 23525 23014 17602 25446 19778 19245 22495 20483 1 20536 18709 20751 19257 18191 1 20583 20390 20726 19395 19828 19127 18981 9834 18533 19974 17930 1 17928 20676 1 20327 1 17696 18096 22459 1 17324 17748 19249 19060 19768 16695 28065 1 27030 28072 28436 25456 25985 25834 29152 28023 29358 27409 29772 29906 27065 26632 28179 27179 26094 30438 26542 24024 30724 29981 27418 19067 27971 23289 24854 27382 28869 29565 25018 26164 1 30227 23398 25027 22962 28043 26255 25973 27287 29870 26682 28909 22775 22742 27451 24676 21793 22668 25010 23619 24631 27444 25431 1 25817 24710 23456 22537 23369 26087 23038 24699 22606 24721 1 23560 22629 23551 23615 24704 Mycalamide A 1 1 1 1 1 1 16647 11268 1 1 1 1 1 3823 21077 15541 8633 5981 40580 34387 6579 1 1 1 1 1 38076 31747 1 1 1 1 11024 6922 63955 49291 19303 16220 40772 31168 1 1 1 1 1 1 1 1 1 1 3434 1 1 1 1 9061 9791 8056 1 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37043 36779 36987 36647 36396 33295 35996 37500 35111 40838 24655 37277 39614 36803 43164 40994 34120 35919 36662 37113 37705 36253 41053 39013 43901 42467 34786 38925 37336 36634 40697 43658 31828 41971 38579 39294 43567 44512 46120 45340 38391 41308 38597 38590 43312 44814 42798 39862 27000 38050 27667 42019 38092 39704 38222 36309 1 22286 30044 39941 35110 33393 30657 35652 36081 34781 25978 32020 37154 31639 29743 35236 40405 34680 37079 34912 39023 36759 24398 36331 33898 37066 39429 39463 40144 39456 36499 38815 37164 38506 38007 35039 26620 32379 36229 36624 35626 35975 36816 25640 1 37169 36808 40940 38847 38240 31476 32082 40584 28921 39902 41975 29785 41691 37858 34313 41616 40910 44800 41499 508.182@9.634001 1 1 4950 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 5089 1 1 4932 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 4455 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 5043 1 1 1 1 1 1 1 1 1 1 1 1 1 C17 Sphinganine 50603 49257 50969 53229 52725 51551 50422 54157 53485 53463 51155 29691 51410 52891 49448 50574 55817 51245 55609 53796 50833 55255 53306 54336 53058 52002 56170 58266 56070 54426 54452 54183 58323 56068 56956 55799 56027 57788 55082 53545 57923 37652 52158 53326 55873 56140 53778 55980 52984 56713 52861 52641 52542 54614 52921 56535 53605 52753 54155 53026 53767 54266 57094 52641 54978 53413 55725 57651 58798 55248 55156 51460 57082 58685 54453 61620 56011 59640 59905 63299 56000 30418 60397 59972 60007 58694 55361 61861 56051 59157 59048 57970 58501 60968 58212 58734 58875 57331 58262 60138 60826 61035 57061 58348 58950 58815 58271 57106 60973 73680 74389 76937 73383 70607 71646 5079 72430 70068 69548 68319 72158 68409 72816 75151 26505 70157 72719 74588 78329 75534 70853 76009 71241 73121 74422 72517 77267 75049 73168 79025 70873 72102 72625 69247 341.2563@9.658865 1 15707 26443 21626 16715 12159 18611 13205 12515 9327 15706 1 1 7063 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10878 1 1 1 1 1 1 1 1 1 1 1 1 9761 1 1 1 1 1 1 9886 1 8431 6208 1 10622 1 1 1 1 1 1 1 1 1 11030 10794 10714 1 1 1 10162 9474 9066 1 1 1 1 1 1 1 1 1 10982 9545 1 1 1 1 1 9682 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 7624 8813 1 7692 9056 9237 1 1 1 1 1 1 1 8937 1 1 LysoPE(0:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z)) 1 1 118342 47815 57073 15716 110113 54481 46041 18223 83332 22285 25516 16894 28364 1 128836 70399 98546 61104 31515 17183 39654 13826 58294 32043 33078 19658 60357 48622 40371 27675 163197 98298 76552 25805 43723 17619 56372 19428 106849 35498 39957 27055 23622 11746 64951 17820 69664 21763 146371 61237 154778 39316 26533 24579 43177 15274 20118 14727 168645 45194 89846 40132 57467 42000 71890 26004 64106 28349 1 1 1 1 6577 1 1 1 5523 1 8158 6118 7540 1 5561 1 27990 11163 12298 6512 1 1 26777 14864 91769 42717 38916 16604 24701 13992 1 1 20823 14131 18333 12301 81047 19174 90804 29172 49638 25018 40254 24538 57794 15819 77685 25778 95125 30474 34878 14578 50187 17566 30679 10349 15285 16376 8358 1 39377 22353 59997 38968 35241 17485 36004 1 61326 25019 56191 11560 23357 13999 336.0684@10.855968 1 1 1 22190 1 20560 1 1 1 1 1 1 1 21609 1 1 21535 1 21914 1 19752 21868 1 1 21367 1 1 21790 1 1 21080 1 20206 20120 20147 1 1 1 1 1 1 1 1 1 1 23827 21146 1 1 1 1 1 1 1 1 1 1 1 20268 1 1 1 1 21827 1 1 1 1 22006 1 1 1 1 1 1 1 1 23532 1 1 1 1 24614 24636 27013 1 1 1 1 1 1 1 1 1 25271 1 1 1 1 1 1 23120 1 1 1 1 1 1 1 1 19506 1 1 1 1 1 1 1 1 1 1 1 1 22208 1 1 1 1 25070 23013 25901 1 21469 22927 1 1 1 1 20379 1 1 19545 1 1 296.075@10.862425 1 1 1 1 10743 1 9919 1 1 1 1 9623 1 10078 1 1 1 1 11163 9249 9703 1 1 1 8341 8996 1 1 1 7003 11478 11018 12624 11223 11278 8827 11216 1 11016 1 1 1 1 1 1 10501 1 8572 10835 7391 1 1 9743 9402 1 8751 1 1 7833 7610 1 8676 1 1 1 1 1 1 9633 9954 11890 1 1 9843 1 7959 10858 11149 1 9877 1 1 11297 1 1 1 12633 10815 1 1 10400 11223 1 1 1 1 12504 1 1 1 1 1 10441 11132 1 1 12789 1 1 1 1 1 1 10888 12259 10070 11225 1 1 1 1 1 1 1 1 1 1 1 9967 1 11146 1 1 1 1 1 1 1 9373 8604 1 1 1 8114 569.25@10.8638 1 1 8261 1 4993 1 8036 4886 1 1 1 1 1 1 1 1 11156 5687 7017 1 1 1 1 1 1 1 1 1 1 1 1 1 13348 1 5798 1 1 1 1 1 8811 1 1 1 1 1 1 1 5743 1 12072 1 12198 1 1 1 4540 1 1 1 1 1 8314 1 1 1 6476 1 7035 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 7465 1 1 1 1 1 1 1 1 1 1 1 6730 1 7622 1 4033 1 1 1 4748 1 6424 1 7708 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 5174 1 1 1 481.3172@10.870312 1 1 56324 1 1 3561 24789 12041 8551 1 34200 6442 1 1 1 1 1 1 3921 1 6786 1 1 1 13411 1 1 1 1 1 1 1 23060 8527 1 1 1 1 1 1 13175 1 1 1 1 1 1 1 1 1 7225 1 1 1 1 1 1 1 1 1 10072 1 13788 1 11599 12469 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 8419 1 1 1 1 1 1 1 1 1 1 1 12361 1 1 1 6010 1 1 1 1 1 17388 1 8134 1 1 1 12881 1 1 1 11634 1 1 1 8249 1 6454 1 1 1 1 1 1 1 1990 1 1 1 1 1 1 1 11499 1 1 1 369.2881@10.878786 1 1 50250 18301 29265 1 39364 13009 10576 1 1 1 1 1 1 1 21341 1 1 1 1 1 1 1 1 1 1 1 1 15363 1 1 32190 15555 15140 1 1 1 14494 1 22415 1 18015 9312 1 1 32948 1 16057 1 10429 1 22358 1 26518 19391 1 1 1 1 1 1 12483 1 18076 1 1 1 1 1 1 1 1 1 1 1 1 1 11767 1 1 1 1 1 1 1 14425 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 21785 1 1 1 1 1 1 1 21119 1 16404 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 329.2563@10.913538 1 1 10863 8625 1 1 1 9460 1 1 1 1 8832 1 1 1 10259 1 1 1 1 1 1 1 1 1 1 1 1 8449 1 1 11284 1 9669 1 1 1 1 1 1 1 1 1 1 1 1 10659 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 8363 1 1 1 9700 7986 1 9400 477.2857@10.915917 1 1 80390 30357 47401 8902 44216 26579 20366 1 33388 6441 25759 15982 39624 8158 81825 36160 48849 25298 33950 1 22074 1 34581 16059 21841 10224 34948 29817 13829 9414 96229 52176 36581 10173 56503 19113 59100 21827 51501 12703 15172 7775 32004 10030 48586 13272 58748 17981 95727 40830 95874 21414 23196 19293 28234 10755 20914 13741 93165 15162 53141 17336 48541 33107 45030 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74640 46857 21892 16320 79130 60726 85862 60483 125675 43774 163491 73656 101875 70239 83347 60577 115675 46340 243263 100287 242697 106492 116416 58226 144371 78412 64987 32612 40503 42311 25526 24346 96196 64255 146344 107137 102671 68222 99802 70019 161459 80819 184273 90910 52539 38700 605.2886@10.94 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 6781 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Glycerophospho-N-Arachidonoyl Ethanolamine 15369 11980 430874 176286 168078 38588 268055 138265 87707 39930 89574 25053 68605 42284 85779 27233 312183 152914 199010 122869 107106 62656 83539 30809 114924 71796 118287 67806 194043 159588 95647 67819 380961 195654 133857 51519 149664 64827 231127 101003 112354 37101 43446 25655 56872 24344 145759 41992 137488 47229 221778 97178 206304 50707 110421 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1 1 5186 4593 1 1 1 1 7001 1 7586 1 7837 1 315.3139@10.928319 14559 14094 14845 12660 14168 13780 15772 14618 14749 12904 13663 15091 15639 15344 13732 1 17005 15424 13549 15139 15648 14508 16498 15450 15990 14245 15346 13238 16919 13075 16523 14492 16388 13292 12614 10299 16086 13665 16228 15418 13647 14486 15042 13893 13966 15197 15986 13434 10574 13832 14635 15591 12887 14326 14850 17129 13915 13888 13569 13203 16508 15523 15697 14174 15501 15084 12178 14689 14944 14049 1 12017 1 11220 10910 10760 1 10897 10005 10744 10799 10036 10060 1 5493 11975 11361 9944 11428 1 9778 11628 1 9721 1 10950 1 10144 8440 11310 9686 10753 1 11134 1 1 1 11037 11305 13121 13257 11234 12247 13343 11393 1 11560 1 12142 13563 10632 12186 5887 12540 12456 7823 12281 12710 8246 1 13796 11828 13317 12759 13837 12404 13405 12811 12518 12600 13047 13079 13719 13485 580.3009@10.927908 1 1 8878 1 5519 1 1 1 1 1 1 1 1 1 1 1 5579 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 11408 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 6507 1 1 1 1 1 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1 1 4128 1 1 1 1 1 1 1 1 1 1 1 3179 1 1 1 14109 6421 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 8497 1 9955 1 1 1 1 1 1 1 7773 1 2456 1 1 1 4580 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 4127 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1084.6466@10.985201 1 1 15134 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 15133 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 10164 1 10999 1 1 1 1 1 1 1 3394 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1060.6464@11.13825 1 1 9750 1 1 1 1 1 1 1 1 3999 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 11391 1 1 1 1 1 1 1 1 1 1 3494 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 39846 1 1 112281 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 15872 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 13417 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 C32 H47 O7 158237 136096 2914489 1341192 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1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 557.2886@10.984864 1 1 22281 7152 6636 1 9126 1 1 1 1 1 1 1 1 1 10108 1 1 1 1 1 1 1 1 1 1 1 5490 1 1 1 27420 11542 6271 1 1 1 1 1 5816 1 1 1 1 1 5999 1 8923 1 27024 7833 33117 1 1 1 1 1 1 1 15298 1 5792 1 7456 1 4989 1 7709 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 10929 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 3627 1 609.308@10.993101 1 1 12848 11819 6173 1 6329 1 1 1 4687 1 1 1 1 1 4267 1 1 1 1 1 1 1 1 1 1 1 5310 1 1 1 12948 6580 1 1 1 1 5029 1 5666 1 1 1 1 1 1 1 7218 1 13445 6579 13537 1 1 1 1 1 1 1 9309 1 1 1 5795 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 7971 1 1 1 1 1 1 1 1 1 1 1 1 1 5839 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 4300 1 1 1 1 1 1 1 C31 H41 O7 1 6288 92377 40196 62740 19004 144610 75473 59849 29422 124896 40077 20652 15299 23526 7381 61288 32984 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